Tuesday, February 19, 2013
Carvone nature
Carvone achromatic to anemic chicken condensate l-and d-two kinds of optical isomers, and added were acclimated in cosmetics is l-body. The atomic weight of 150.22. Density 0.96g/cm3. Unique point of 231 ° C. A beam point of 92 ℃. Insoluble in water. Oil-soluble and alcohol. L: 2 was attenuated in 70% ethanol. Has balm agnate spearmint. It is an important spice, it is broadly acclimated in the aliment industry and the actinic industry, toothpaste, harder candy, chewing gum, and a array of beverages, so the (-) - carvone amalgam has important bread-and-butter value. This artefact is hardly adverse to water, do not acquiesce undiluted artefact or ample amount of the artefact to ability arena water, baptize advance or carrion system, and not acquiesce actual to be appear to the ambiance after able authoritative permits. Using nitroso chloride law. Limonene as a raw material, generated chlorine acknowledgment with nitroso limonene nitroso chloride, again dehydrochlorinated to accomplish l-oxime, and assuredly had been hydrolyzed. Can aswell be extracted from spearmint capital oils by beverage derived. Amalgam of ketones. Mainly acclimated as a the floral aroma aggregate spices.
Carvone was acclimated for alleviative purposes by the age-old Romans, but carvone was apparently not abandoned as a authentic admixture until Franz Varrentrapp (1815-1877) acquired it in 1849. It was originally alleged carvol by Schweizer. Goldschmidt and Zűrrer articular it as a ketone accompanying to limonene, and the anatomy was assuredly elucidated by Georg Wagner (1849-1903) in 1894. The dextro-form is acquired about authentic by the apportioned beverage of caraway oil; the levo-form from the oils absolute it, by aboriginal basic its accession admixture with hydrogen sulfide, decomposing this by potassium hydroxide in ethanol, and distilling the artefact in a accepted of steam. It may be synthetically able from limonene nitrosochloride, alcoholic converting this admixture into 1-carvoxime, which on baking with adulterate sulfuric acerbic yields l-carvone. The above use of d-limonene is as a forerunner to carvone. The ample calibration availability of orange rinds, a byproduct in the assembly of orange juice, has fabricated limonene cheaply available, and constructed carvone appropriately inexpensively prepared.
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from: Chemical Reagent
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